Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: efficient synthesis of indolizines† †Electronic supplementary information (ESI) available: Experimental procedures and characterization for new compounds are provided. See DOI: 10.1039/c4sc03358b

Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: efficient synthesis of indolizines

The transition-metal-catalyzed denitrogenative transannulation of pyridotriazoles represents an efficient method for the synthesis of fused nitrogen-containing heterocycles. This method is based on the ability of pyridotriazole to exist in an equilibrium with diazo-form A, which can be trapped with Rh(II) to form the reactive pyridyl carbene intermediate B, capable of reacting with terminal alk...

Copper-catalyzed aminoalkynylation of alkenes with hypervalent iodine reagents† †Electronic supplementary information (ESI) available: Characterization data and experimental procedures. CCDC 1567005–1567007. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc03420b

A copper-catalyzed aminoalkynylation of alkenes is achieved with ethynylbenziodoxolone (EBX) reagents under mild conditions with only 1 mol% copper catalyst. This transformation allows for rapid construction of diverse important azahetereocycles and installation of valuable alkyne groups in one step. The developed method features remarkable substrate scope for both terminal and internal alkenes...

Rh-catalyzed aerobic oxidative cyclization of anilines, alkynes, and CO† †Electronic supplementary information (ESI) available: Experimental details and spectral data. See DOI: 10.1039/c7sc02181j Click here for additional data file.

Copper-catalyzed dehydrogenative borylation of terminal alkynes with pinacolborane† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc02668k Click here for additional data file.

A. General Considerations ................................................................................................................................2 B. Optimization Tables for the Dehydroborylation Reaction............................................................2 C. Catalytic procedure for the Dehydroborylation Reaction .............................................................3 D...

Palladium(ii)-catalyzed synthesis of dibenzothiophene derivatives via the cleavage of carbon–sulfur and carbon–hydrogen bonds† †Electronic supplementary information (ESI) available: Experimental procedures and characterization data for all new compounds. See DOI: 10.1039/c5sc04890g Click here for additional data file.